{"created":"2023-06-19T11:10:19.489875+00:00","id":465,"links":{},"metadata":{"_buckets":{"deposit":"b9a21743-aedd-4cf4-ad00-afb6edbf1a1e"},"_deposit":{"created_by":2,"id":"465","owners":[2],"pid":{"revision_id":0,"type":"depid","value":"465"},"status":"published"},"_oai":{"id":"oai:fukuoka-edu.repo.nii.ac.jp:00000465","sets":["69:70"]},"author_link":["1366","1365"],"item_18_alternative_title_16":{"attribute_name":"その他の言語のタイトル","attribute_value_mlt":[{"subitem_alternative_title":"Zn-Fe-Ga-Sケイ ノ ソウヘイコウ ケンキュウ"}]},"item_18_biblio_info_7":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"1999-03","bibliographicIssueDateType":"Issued"},"bibliographic_titles":[{}]}]},"item_18_description_12":{"attribute_name":"フォーマット","attribute_value_mlt":[{"subitem_description":"application/pdf","subitem_description_type":"Other"}]},"item_18_description_19":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"subitem_description":"Technical Report","subitem_description_type":"Other"}]},"item_18_description_4":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"増設した電気炉及び電子天秤を用いて、Zn-Fe-Ga-S四成分系の900℃及び800℃での乾式法による相平衡実験を行い、両温度での四成分相平衡関係を明らかにした。反応物質は合成のZnS,FeS,GaS,Ga_2S_3,、元素のZn,Fe,Ga,Sの計8種類である。生成物はice water-quenching後、反射顕微鏡及びX線回折法により同定された。同定された相は以下の通りである。 sphalerite,wurtzite,Alloy Y,Phase X,Phase Z,Phase U,Phase V,Phase W,pyrrhotite,α-iron,zinc-liquid,gallium-liquid,sulfur- liquid,GaS,Ga_2S_3. この四成分系の中心をなす最も大きな固溶体は(Zn,Fe,Ga)_<1-X>S固溶体である。次に比較的大きな固溶体範囲を示すのは Phase V固溶体である。これはUeno&Scott(1995)によりZn-Ga-S系の正方晶系の相として報告されたが、 Ueno,Scott&KoJima(1996)により示された様に、Feもかなり固溶するためZn-Fe-Ga-S四成分の固溶体となっている。その他Zn-Ga-S面内には立方晶系のPhase U固溶体が存在するが、Feはほとんど固溶しない。Ga-Fe-S面内には閃亜鉛鉱型構造をもつ立方晶系のPhase Z固溶体、六方晶系のPhase W,正方晶系のPhase Xが存在する。Phase XはZnを若干固溶するがPhase Z固溶体及びPhase Wは固溶しない。Zn-S上は閃亜鉛鉱型のZnSのみが、Fe-S上はPyrrhotite固溶体のみが存在し、GaとZnを若干固溶する。Ga-S上にはGaS,Ga_2S_3が存在し、それぞれ小さな固溶体範囲を持っている。Zinc-liquidはGaよりもFeを多く、又Gallium- liquidはFeよりもZnを多く固溶する。又FeはFe-Ga上にα-ironとAlloy Yの固溶体領域を持ち、Fe-Zn上にγ-phaseの固溶体領域を持つ。","subitem_description_type":"Abstract"}]},"item_18_description_5":{"attribute_name":"内容記述","attribute_value_mlt":[{"subitem_description":"平成9～10年度科学研究費補助金（基盤研究(C)(2)）研究成果報告書(課題番号09640573)","subitem_description_type":"Other"}]},"item_18_full_name_2":{"attribute_name":"著者（ヨミ）","attribute_value_mlt":[{"nameIdentifiers":[{"nameIdentifier":"1366","nameIdentifierScheme":"WEKO"}],"names":[{"name":"ウエノ, テイイチ"}]}]},"item_18_publisher_18":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"福岡教育大学"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"上野, 禎一"}],"nameIdentifiers":[{"nameIdentifier":"1365","nameIdentifierScheme":"WEKO"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2020-09-28"}],"displaytype":"detail","filename":"ueno_kaken_9~10.pdf","filesize":[{"value":"4.6 MB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"ueno_kaken_9~10.pdf","url":"https://fukuoka-edu.repo.nii.ac.jp/record/465/files/ueno_kaken_9~10.pdf"},"version_id":"18868c08-061e-4ca4-a7a1-fe0c67eae795"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"ETYP:教育関連論文","subitem_subject_scheme":"Other"},{"subitem_subject":"Zn-Fe-Ga-S system","subitem_subject_scheme":"Other"},{"subitem_subject":"Zn-Fe-Ga-S系","subitem_subject_scheme":"Other"},{"subitem_subject":"dry method","subitem_subject_scheme":"Other"},{"subitem_subject":"mineral synthesis","subitem_subject_scheme":"Other"},{"subitem_subject":"phase equilibrium","subitem_subject_scheme":"Other"},{"subitem_subject":"phase inversion","subitem_subject_scheme":"Other"},{"subitem_subject":"sphalerite","subitem_subject_scheme":"Other"},{"subitem_subject":"sulfide","subitem_subject_scheme":"Other"},{"subitem_subject":"wurtzite","subitem_subject_scheme":"Other"},{"subitem_subject":"ウルツ鉱","subitem_subject_scheme":"Other"},{"subitem_subject":"乾式法","subitem_subject_scheme":"Other"},{"subitem_subject":"熱水合成法","subitem_subject_scheme":"Other"},{"subitem_subject":"相平衡","subitem_subject_scheme":"Other"},{"subitem_subject":"相転移","subitem_subject_scheme":"Other"},{"subitem_subject":"硫化鉱物","subitem_subject_scheme":"Other"},{"subitem_subject":"鉱物合成","subitem_subject_scheme":"Other"},{"subitem_subject":"閃亜鉛鉱","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"jpn"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"research report","resourceuri":"http://purl.org/coar/resource_type/c_18ws"}]},"item_title":"Zn-Fe-Ga-S系の相平衡研究","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Zn-Fe-Ga-S系の相平衡研究"}]},"item_type_id":"18","owner":"2","path":["70"],"pubdate":{"attribute_name":"公開日","attribute_value":"2010-06-01"},"publish_date":"2010-06-01","publish_status":"0","recid":"465","relation_version_is_last":true,"title":["Zn-Fe-Ga-S系の相平衡研究"],"weko_creator_id":"2","weko_shared_id":-1},"updated":"2023-06-19T12:48:07.548561+00:00"}