{"created":"2023-06-19T11:10:49.549892+00:00","id":975,"links":{},"metadata":{"_buckets":{"deposit":"8d6ccc80-799f-44fd-bf1e-18d7219c1c70"},"_deposit":{"created_by":5,"id":"975","owners":[5],"pid":{"revision_id":0,"type":"depid","value":"975"},"status":"published"},"_oai":{"id":"oai:fukuoka-edu.repo.nii.ac.jp:00000975","sets":["71:74:1715571892996"]},"author_link":["72","3094","3095"],"item_16_biblio_info_7":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2020-03-10","bibliographicIssueDateType":"Issued"},"bibliographicPageEnd":"24","bibliographicPageStart":"19","bibliographicVolumeNumber":"69","bibliographic_titles":[{"bibliographic_title":"福岡教育大学紀要. 第三分冊, 数学・理科・技術科編"},{"bibliographic_title":"Bulletin of University of Teacher Education Fukuoka. Part III, Mathematics, natural sciences and technology"}]}]},"item_16_description_4":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"キラルなエポキシドは，天然有機化合物の構成要素として存在するだけでなく，合成中間体としての価値が高いことから，その不斉合成法は古くから活発に研究されている。本研究では，入手容易な市販のキラルジアミンの一方をアルキル置換したジアミン触媒を用いて，カルコンの不斉エポキシ化の検討を行った。その結果，化学収率は 49% と中程度であったが，92% ee の高い不斉収率を得ることができた。これらの詳細について報告する。","subitem_description_type":"Abstract"}]},"item_16_radio_19":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"subitem_radio_item":"紀要論文 Article"}]},"item_1714138083653":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"0532-811X","subitem_source_identifier_type":"PISSN"}]},"item_1714138754612":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"福岡教育大学"}]},"item_access_right":{"attribute_name":"アクセス権","attribute_value_mlt":[{"subitem_access_right":"open access","subitem_access_right_uri":"http://purl.org/coar/access_right/c_abf2"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"伊藤, 克治","creatorNameLang":"ja"},{"creatorName":"ITO, Katsuji","creatorNameLang":"en"},{"creatorName":"イトウ, カツジ","creatorNameLang":"ja-Kana"}],"familyNames":[{"familyName":"伊藤","familyNameLang":"ja"},{"familyName":"ITO","familyNameLang":"en"},{"familyName":"イトウ","familyNameLang":"ja-Kana"}],"givenNames":[{"givenName":"克治","givenNameLang":"ja"},{"givenName":"Katsuji","givenNameLang":"en"},{"givenName":"カツジ","givenNameLang":"ja-Kana"}],"nameIdentifiers":[{"nameIdentifier":"72","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"宮城, 良輔","creatorNameLang":"ja"},{"creatorName":"ミヤシロ, リョウスケ","creatorNameLang":"ja-Kana"},{"creatorName":"MIYASHIRO, Ryosuke","creatorNameLang":"en"}],"familyNames":[{"familyName":"宮城","familyNameLang":"ja"},{"familyName":"ミヤシロ","familyNameLang":"ja-Kana"},{"familyName":"MIYASHIRO","familyNameLang":"en"}],"givenNames":[{"givenName":"良輔","givenNameLang":"ja"},{"givenName":"リョウスケ","givenNameLang":"ja-Kana"},{"givenName":"Ryosuke","givenNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"3094","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"山﨑, 健太郎","creatorNameLang":"ja"},{"creatorName":"ヤマサキ, ケンタロウ","creatorNameLang":"ja-Kana"},{"creatorName":"YAMASAKI, Kentaro","creatorNameLang":"en"}],"familyNames":[{"familyName":"山﨑","familyNameLang":"ja"},{"familyName":"ヤマサキ","familyNameLang":"ja-Kana"},{"familyName":"YAMASAKI","familyNameLang":"en"}],"givenNames":[{"givenName":"健太郎","givenNameLang":"ja"},{"givenName":"ケンタロウ","givenNameLang":"ja-Kana"},{"givenName":"Kentaro","givenNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"3095","nameIdentifierScheme":"WEKO"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2020-09-28"}],"displaytype":"detail","filename":"3-03-伊藤 克治.pdf","filesize":[{"value":"2.8 MB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"3-03-伊藤 克治.pdf","url":"https://fukuoka-edu.repo.nii.ac.jp/record/975/files/3-03-伊藤 克治.pdf"},"version_id":"6aee5860-0414-4fcb-995b-3bde07f2214f"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"ETYP:教育関連論文","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"jpn"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"departmental bulletin paper","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"ジアミン触媒を用いるカルコンの不斉エポキシ化","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"ジアミン触媒を用いるカルコンの不斉エポキシ化","subitem_title_language":"ja"},{"subitem_title":"ジアミン ショクバイ オ モチイル カルコン ノ フセイ エポキシカ","subitem_title_language":"ja-Kana"},{"subitem_title":"Enantioselective Epoxidation of Chalcone Using Diamine Catalysts","subitem_title_language":"en"}]},"item_type_id":"16","owner":"5","path":["1715571892996"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2020-03-13"},"publish_date":"2020-03-13","publish_status":"0","recid":"975","relation_version_is_last":true,"title":["ジアミン触媒を用いるカルコンの不斉エポキシ化"],"weko_creator_id":"5","weko_shared_id":-1},"updated":"2024-05-23T05:20:59.017021+00:00"}